1)
Synthesis 2000; 2000: 970-974
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http://dx.doi.org/10.1055/s-2000-6294Sulfur-Alkyne Cyclizations for Formation of Dihydrothiophenes and Annulated Thiophenes
Cycloisomerization of homopropargylic thiols to dihydrothiophenes is promoted by group VI metal carbonyls. Related thiacyclization transformations under basic and radical conditions are also described, including regioselective formation of benzothiophenes from aryl methyl sulfides and alkynes.
2)
Synthetic Communications. Volume 26, Issue 7 April 1996 , pages 1363 — 1370
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http://dx.doi.org/10.1080/00397919608003497Studies Directed Toward the Regioselective Carboxylation of the 4-Oxo-4,5,6,7-Tetrahydrothieno-[3,2-C]pyridine Ring System
Carboxylation of 4-oxo-4,5,6,7-tetrahydro[3,2-c]pyridine was achieved using a metallation/carbonylation strategy with desired regioselectivity provided by the existing oxo directing group.