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Нужна полна ссылка с названием статьи в уже несуществующем журнале:
A. Hirsch and B. E. Brigland. ???? Can. Spectroscopy 1967, 12, 101-???
+++Can.Spectroscopy 1967, 12, 101 - полная ссылка
Re: Can.Spectroscopy 1967, 12, 101 - полная ссылка
CAS писал(а):TI Continuous monitoring of reactions via infrared spectroscopy
AU ***Hirsch, A.*** ; Bridgland, B. E.
CS Can. Tech. Tape. Ltd., Montreal, Can.
SO ***Canadian Spectroscopy*** ( ***1967*** ), 12(3), 101-4
CODEN: CASPAN; ISSN: 0008-5057
AB A flow technique is described for the continuous monitoring of chem.
reactions, which consists of circulating the soln. in a reaction vessel
through a 1-mm. sealed KBr cell in a recording ir spectrophotometer. It
is essential that a unique wavelength be found characteristic of the
extent of the reaction and at which Beer's law is obeyed. For reaction
times of 1-2 hrs. (or more), the delay in sensing and recording is
insignificant. The rate const. and order of the reaction can be found
graphically. This has been done for (a) the carbonation of n-propylamine,
(b) the addn. of benzyl alc. to phenyl isocyanate, and © the
polymerization of ethyl acrylate.
Re: Can.Spectroscopy 1967, 12, 101 - полная ссылка
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