М.б. чрезмерно напрягаю, но хотелось бы ознакомиться с книгой (если у кого-нибудь есть доступ)
Author(s): Christian Laurence, Jean-Franзois Gal
Lewis Basicity and Affinity Scales
Published Online: 23 Dec 2009
Код: Выделить всё
http://dx.doi.org/10.1002/9780470681909Short description
Lewis Basicity and Affinity Scales provides a comprehensive range of Lewis basicity/affinity data in one volume. More than 2400 equilibrium constants of acid-base reactions, 1500 complexation enthalpies, and nearly 2000 infrared and ultraviolet shifts upon complexation are gathered together in 25 thermodynamic and spectroscopic scales of basicity and/or affinity. For each scale, the definition, the method of measurement, an exhaustive database, and a critical discussion are given. This is an essential single-source desktop reference for research scientists, engineers, and students in academia, research institutes and industry, in all areas of chemistry from fundamental to applied research.
Chapter 1 Lewis basicity and affinity measurement: definitions and context
Chapter 2 The Donor Number or SbCl5 affinity scale
Chapter 3 The BF3 affinity scale
Chapter 4 Thermodynamic and spectroscopic scales of hydrogen-bond basicity and affinity
Chapter 5 Thermodynamic and spectroscopic scales of halogen-bond basicity and affinity
Chapter 6 Gas-phase cation basicity and affinity scales
Chapter 7 The measurement of Lewis basicity and affinity in the laboratory