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Хотелось бы посмотреть две статьи:
1. Potential energy hypersurface determination for non-rigid molecules. II. Single, double internal rotation,next term and wagging vibration modes
Y. G. Smeyers, M. N. Bellido and A. Niño
Journal of Molecular Structure: THEOCHEM
Volume 166, June 1988, Pages 1-10

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http://dx.doi.org/10.1016/0166-1280(88)80409-3

2.Raman spectrum, conformational stability, barriers to internal rotationsnext term and DFT calculations of 1,1,1-trifluoro-propane-2-thione with previous termdouble-internalnext term-symmetric rotor
Tarek A. MohamedCorresponding Author Contact Information, a, E-mail The Corresponding Author and Rabei S. Farag
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Volume 62, Issues 4-5, December 2005, Pages 800-807

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http://dx.doi.org/10.1016/j.saa.2005.03.007

Заранее, очень благодарен!!!

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