1) Innate C-H trifluoromethylation of heterocycles
Yining Ji, Tobias Brueckl, Ryan D. Baxter, Yuta Fujiwara, Ian B. Seiple, Shun Su, Donna G. Blackmond, and Phil S. Baran
PNAS 2011 ; published ahead of print August 15, 2011
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http://dx.doi.org/10.1073/pnas.1109059108