+++Annali di Chimica

[NikChemist]

Здравствуйте, помогите, пожалуйста, найти статьи:
1) Ciavatta, Annali di Chimica, v.91, p245
2) Salvatore, Annali di Chimica, v.80, p.515
Заранее благодарен!

[amik]

Плюсики из заголовка пока удалил. Они ставятся, когда запрос выполнен, см. правила

[Ol.Lo]

Добрый день!
Как ни крути, библиографию надо давать полностью.

[mishka]

Для 1 библиография:
On the formation of iron(III) hydroxo acetate complexes.

Authors
Ciavatta L1, De Tommaso G, Iuliano M.
Author information
1Dipartimento di Chimica dell'Università Federico II, Via Cinthia, 80126 Napoli. ciavatta@chemistry.unina.it

Annali di Chimica: Vol. 91, No. 5-6, 2001, p. 245-254

Abstract
The formation of hydroxo acetate complexes of iron (III) ion has been studied at 25 degrees C in 3 M (Na)ClO4 ionic medium by measuring with a glass electrode the hydrogen ion concentration in Fe(ClO4)3-HClO4-NaAc mixtures (Ac = acetate ion). The acetate/metal ratio ranged from 0 to 6, the metal concentration varied from 0.005 to 0.06 M, whereas [H+] was stepwise decreased from 0.1 M to initial precipitation of hydroxo-acetates. This occurred, depending on the acetate/metal ratio, in the -log[H+] range 1.85-2.7. The potentiometric data are consistent with the presence of Fe3(OH)3Ac3(3+), Fe2(OH)2(4+), Fe3(OH)4(5+), Fe3(OH)5(4+) and, as minor species, of Fe3(OH)2Ac6+, FeAc2+, FeAc2+, FeOH2+ and Fe(OH)2+. Previously published EMF measurements with redox and glass half-cells were recalculated to refine the stability constants of FeAc2+, FeAc2+ and Fe3(OH)2Ac6+. Formation constants *beta pqr for pFe(3+)+(q-r)H2O + rHAc reversible Fep(OH)(q-r)(Ac)r3p-q + qH+ (in parenthesis the infinite dilution value): log*beta 111 = -1.85 +/- 0.02 (-0.67 +/- 0.15), log*beta 122 = -3.43 +/- 0.02 (-1.45 +/- 0.15); log*beta 363 = -5.66 +/- 0.03 (-2.85 +/- 0.40), log*beta 386 = -8.016 +/- 0.006 (-4.06 +/- 0.15), log*beta 220 = -2.88 +/- 0.02 (-2.84 +/- 0.05), log*beta 340 = -6.14 +/- 0.18 (-6.9 +/- 0.4), log*beta 350 = -8.44 +/- 0.09 (-7.65 +/- 0.15).

[mishka]

Для 2:
Francesco Salvatore, Ermanno Vasca. Formation constants of FeOH2+, (FeOH)2+ and Fe2(OH)24+ at zero ionic strengh.
Annali di Chimica. 1990, vol.80, P. 515–520

[Ol.Lo]

Спасибо, mishka.

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[NikChemist]

спасибо огромное всем за помощь!!!