+++ Поиск в Reaxys или SF, спасибо mishka

[ArshEV]

Здравствуйте, помогите найти методы синтеза данных соединений:
1) C1(=C(C(=C(C(=C1C(\C(=C(\C2=C(C(=C(C(=C2[H])Br)[H])[H])[H])[H])[H])=O)[H])[H])[H])[H])[H]
2) C1(=C(C(=NC(=C1C#N)C([H])([H])[H])C2=C(C(=C(C(=C2[H])[H])C([H])([H])[H])[H])[H])[H])C3=C(C(=C(C(=C3[H])[H])C([H])([H])[H])[H])[H]
3) C1(=C(C(=NC(=C1C#N)C([H])([H])[H])C2=C(C(=C(C(=C2[H])[H])Br)[H])[H])[H])C3=C(C(=C(C(=C3[H])[H])[H])[H])[H]
4) C1(=C(C(=NC(=C1C#N)C([H])([H])[H])C2=C(C(=C(C(=C2[H])[H])[H])[H])[H])[H])C3=C(C(=C(C(=C3[H])Br)[H])[H])[H]
Заранее спасибо!

[mishka]

реакс
есть только 1