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В.
Журн. неорг. хим. т. V, № 3, 558 (1960)
Название: Ацетаты алюминия
Al(OAc)3 dissolves easily in liquid NH3. On evaporation, Al(OAc)3.3NH3 is obtained which loses NH3 at room temperature Al(OAc)3 is also soluble in liquid SO2 and in anhydrous ethylenediamine. The latter solution becomes gelatinous with time. Thermal decomposition of Al(OAc)3 begins at 120-40°; 2Al(OAc)3 → Al2O(OAc)4 + Ac2O. The next step of decomposition occurs at 200° and leads to AlO(OAc). The thermal decomposition of Al(OH)(OAc)2 (I) occurs at 250-300° with the formation of MO(OH) and Ac2O in one step only, thus confirming formula I and not Al2O(OAc)4.H2O. I is insoluble in organic solvents and liquid NH3, slightly soluble in liquid SO2 and CHCl3. It forms hydrates with 2 and 2.5 H2O. X-ray patterns of all investigated acetates are given.
